Cobalt, nickel, wolfram, cadmium, selenium, silver and gold-bearing mercurian tetrahedrite from the Saski Rad barite-siderite deposit in the Mid-Bosnian Schist Mts.
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Published:
Sep 15, 2011
Keywords:
Mercurian tetrahedrite, content of Co, Ni, W, Cd, Se, Ag and Au, sulphur isotope compositions, Saski Rad and Rad barite-siderite deposits, Palaeozoic, Mid-Bosnia
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Abstract
In the Saski Rad barite-siderite ore deposit, Hg-tetrahedrite is the main ore mineral, pyrite and some others are only accessories. Two tetrahedrite samples (fresh and weathered) have been analysed in detail: major and minor components, constituent trace elements, REE, and δ34SCDT values. The following microconstituents have been detected: Ni 71 ppm (in fresh sample) and 70 ppm (in weathered sample); Co 113 and 90 ppm; Cd 27 and 20 ppm; W 20 and 5 ppm, Bi 2500 and 1613 ppm; Se >100 and 72 ppm and Au 11 and 9 ppm. These values have been compared with the only currently available analysis of Hg-tetrahedrite from the Duboki Vagan near Kreševo in the Mid-Bosnian Schist Mts. (MBSM) carried out by JURKOVIĆ et al. (2010): Ni 266.2 ppm; Co 63.5 ppm, Cd 319.6 ppm; Bi 1466.0 ppm; Au 38.96 ppm which also agrees with our analysis of Hg-tetrahedrite from the Brixlegg barite deposit in Tyrol, Austria: Co 234.4 ppm; Cd 160.5 ppm; W 6.7 ppm; Sn 1.0 ppm; Bi 909.1 ppm; Se > 100 ppm and Au 2.3 ppm. The δ34SCDT isotope values of six tetrahedrites from the Saski Rad are on average –10.11‰, those of three tetrahedrites from the Duboki Vagan –10,05‰ and of the tetrahedrite from the Brixlegg deposit –1.60‰. The ΣREE content is lower in two analysed tetrahedrites from the Saski Rad deposit (10 ppm) compared to the tetrahedrite from Duboki Vagan (15 ppm) and the tetrahedrite from Brixlegg (17.4 ppm). The analysed barite sample from the Saski Rad deposit does not contain microconstituents typical of Hg-tetrahedrite. The distribution and genetic signifi cance of some trace elements, tetrahedrite microconstituents, REE and siderite isomorphic components in the seven most important genetic and paragenetic types of ore deposits in the MBSM and South-Eastern Bosnia have been commented upon.
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References
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FOIT JR., F. F. & HUGHES, M. J. (2004): Structural variations in mer-curian tetrahedrite.– American Mineralogist, 89, 159–163.
FRIMMEL, H.E. & PAPESH, W. (1990): Sr, O, and C Isotope Study of the brixlegg Barite Deposit, Tyrol (Austria).– Econ. Geology, 85, 1162–1171.
GRECULA, P., RADVANEC, M. & ŽÁK, K. (1989): Metamorphic ori-gin of hydrothermal ore fl uids of vein mineralization in the gemeri-cum belt, Western Carpathians. 28th International Geological Con-gress, Washington, USA. Abstract Volume, 584–585.
GSTREIN, P. (1983): Ueber mögliche Umlagerungen fon Fahlerzen im devonischen Schwazer Dolomit wie auch in der angrenzenden Schwazer Trias. Oester. Akad. D. Wissench., 6.– In “Ore Mobiliza-tion in the Alps and in SE-Europe”, Leoben-Wien, 65–74.
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JOHNSON, N.E., CRAIG, J.R. & RIMSTIDT, J.D. (1988): Crystal che-mistry of tetrahedrite.– American Mineralogist, 73, 389–397.
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JURKOVIĆ, I. (1956): Mineralne parageneze Srednjobosanskog Rudog-orja s osobitim osvrtom na tetraedrite [Mineral parageneses of the Mid-Bosnian Ore Mountains with particular respect on tetrahe-drites – in Croatian].– Unpubl. PhD theses, University of Zagreb. 306 p.
JURKOVIĆ, I. (1958): Kasiterit, stanin i molibdenit u rudnoj pojavi Vrt-lasce kod Klisca [Cassiterite, stannite and molybdenite from the ore occurrence Vrtlasce at Klisac – in Croatian].– Geol. glasnik, 4, Sarajevo, 1958, 309–320.
JURKOVIĆ, I. (1960): Quecksilberfahlerz vom Mačkara Gang bei Gornji Vakuf in Bosnien.– Neues Jh.d.Mineral., Abh. 94, Stuttgart, 539–558.JURKOVIĆ, I. (1962): Parageneze rudnih pojava u oblasti Čemernice kod Fojnice [Parageneses of ore occurrences in the area of Čemer-nica near Fojnica – in Croatian].– Geol. glasnik, 6, Sarajevo 1962, 141–156.
JURKOVIĆ, I. (1986): Quantitative Chemical and Optical Investigations of the Tetrahedrite from Barite-bearing Deposit Vidici on the North-ern Slopes of the Mountain Međuvršje, South of the Town of Kre-ševo, Bosnia.– Geološki vjesnik, 39, 187–224.
JURKOVIĆ, I. (1987): Barite Deposits on Mount Međuvršje South and South-East of the Town of Kreševo, Bosnia.– Geol. vjesnik, 40, 313–336.
JURKOVIĆ, I. (1995): Bakovići, the biggest gold deposit of Bosnia and Herzegovina.– Rud. geol. naftni zbornik, 7, 1–15.
JURKOVIĆ, I. & HRVATOVIĆ, H. (in press): Geology, petrology and geochemistry of the Mačje Jame and Vranjska Rijeka iron ore de-posits, Mid-Bosnian Schist Mountains.JURKOVIĆ, I., ŠIFTAR, D. & PEZDIČ, J. (1994): Geology and geo-chemistry of the mineralization from the Gornji Vakuf, Bosnia.– Rudarsko-geološko-naftni zbornik, 6, 19–37.
JURKOVIĆ, I. & MAJER, V. (1954): Rioliti (kremeni porfi ri) Vranice planine i albitski riolit Sinjakova u Srednjobosanskom Rudogorju [Rhyolites-quartzporphyries – of the Vranica Mountain and albite rhyolite of Sinjakovo in the Mid-Bosnian Ore Mountains – in Cro-atian].– Vjesnik Zavoda za geološka i geofi zička istraživanja NR Srbije, XI, Beograd, 207–233.
JURKOVIĆ, I. & MIKO, S. (1997): Tetrahedrite from the Dubrave-Dugi Dol Barite Deposit, Kreševo, Bosnia and Herzegovina.– Rudarsko-geološko-naftni zbornik, 9, 11–16.JURKOVIĆ, I. & PALINKAŠ, L. (1999): Sulphur isotope and fl uid inclu-sion data of barites from the Dinarides.– Sixth Biennal Meeting of SGA and IAGOD.– Mineral Deposits, Processes to Processing, Lon-don, 1999. Proceedings, Balkema, pub., Rotterdam, 1999, 45–49.
JURKOVIĆ, I. & PALINKAŠ, L. (1996): Late Variscan, Middle-Upper-Permian, post-Variscan and Triassic rifting related ore de posits in the Northwestern and central Dinarides.– Proceeding of the Annu-al Meeting, UNESCO Project No. 356, Plate Tectonic Aspects of the Alpine Metallogeny in the Carpatho-Balkan Region, Sofi a, 1, 19–27.
JURKOVIĆ, I. & PALINKAŠ, L. (2002): Discrimination criteria for as-signig ore deposits located in the Dinaridic Palaeozoic-Triassic for-mations to Variscan or Alpidic metallogeny.– In: BLUNDELL, D.J, NEUBAUER, F. & VON QUADE, A. (eds.): The Timming and Location of Major Ore Deposits in an orogen. Geological Society, London, Special Publications, 204, 229–245.
JURKOVIĆ, I., GARAŠIĆ, V. & HRVATOVIĆ, H. (2010): Geochemi-cal characteristics of barite occurrences in the Palaeozoic complex of South-eastern Bosnia and their relationship to the barite deposits of the Mid-Bosnian Schist Mountains.– Geol. Croat., 63/2, 241–258.
JURKOVIĆ, I., RAMOVIĆ, M. & ZEC, F. (1999): Chemical and geo-chemical characteristics of the Čemernica antimonite deposit in the Mid-Bosnian Schist Mountains.– Rud.-geol.-nafnti zbornik, 11, 1–16.
JURKOVIĆ, I.B., GARAŠIĆ, V. & JURKOVIĆ, I.M. (2011): Geochem-ical characteristics of mercurian tetrahedrite, barite and fl uorite from the Duboki Vagan, Glumac and Dubrave-Dugi Dol barite deposits, south of Kreševo, Mid-Bosnian Schist Mts.– Geol. Croat., 64/1, 49–59.
JURKOVIĆ, I., TONČIĆ-GREGL, R., STRMIĆ, S. & ŠIFTAR, D. (2002): Geology and geochemistry of the Raštelica barite deposits southwest of Sarajevo, Bosnia and Herzegovina.– Rud.-geo.-naftni zbornik, 14, 37–46.
JURKOVIĆ, I., PALINKAŠ, L, ŠIFTAR, D., MIKO, S., JAKŠIĆ, M. & PEZDIČ, J. (1997): Gechemical characteristics of mercurian tetra-hedrites from the Mid-Bosnien Schist Mts.– The 4th SGA Meeting, Finland. Published by Balkema, Rotterdam, 829–833.
KATZER, F. (1907): Die Fahlerz– und Quecksilbererzlagerstätten Bos-niens und der Hercegovina.– Berg-und Hüttenmännisches Jahr-buch der k. k. montanist. Hochschulen zu Leoben und Pribram. LV 2, 121 p.
KATZER, F. (1926): Geologie Bosniens und der Herzegovina.– Erster Band, I. u II. Hälfte, Sarajevo.
KUBAT, I., RAMOVIĆ, E., TOMIČEVIĆ, D., PEZDIČ, J. & DOLE-N EC, T. (1979/80): Results of the investigations of isotopic com-positions of sulphur, oxygen, carbon and lead in some ore deposits and ore occurrences from Bosnia and Herzegovina (in Bosnian).– Geol. glasnik, 24–25, 61–84.
KULENOVIĆ, E. (1987): Mineralizacije u paleozoiku Jugoistočne Bosne [Mineralisation in Palaeozoic of South-eastern Bosnia – in Serbian].– Geol. glasnik, 31/31, 106–143.
LUKAS, W. (1971): Tektonisch-genetische Untersuchung der fahlerz – Lagerstätte am Falkenstein bei Schwaz (Tirol).– N. Jb. Geol. Palä-ont. Mh, 47–63.
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